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Integrated luminometer for the determination of trace metals in seawater using fluorescence, phosphorescence and chemiluminescence detection
Worsfold, P.J.; Achterberg, E.P.; Bowie, A.R.; Cannizzaro, V.; Charles, S.; Costa, J.M.; Dubois, F.; Pereiro, R.; San Vicente, B.; Sanz-Medel, A.; Vandeloise, R.; Vander Donckt, E.; Wollast, P.; Yunus, S. (2002). Integrated luminometer for the determination of trace metals in seawater using fluorescence, phosphorescence and chemiluminescence detection. J. Autom. Methods Manag. Chem. 24(2): 41-47
Peer reviewed article  
Available in  Authors 
Keywords
    Marine/Coastal; Brackish water
Authors  Top 
  • Worsfold, P.J.
  • Achterberg, E.P.
  • Bowie, A.R.
  • Cannizzaro, V.
  • Charles, S.
  • Costa, J.M.
  • Dubois, F.
  • Pereiro, R.
  • San Vicente, B.
  • Sanz-Medel, A.
  • Vandeloise, R.
  • Vander Donckt, E.
  • Wollast, P.
  • Yunus, S.
Abstract
    The paper describes an integrated luminometer able to perform fluorescence (FL), room temperature phosphorescence (RTP) and chemiluminescence (CL) measurements on seawater samples. The technical details of the instrumentation are presented together with flow injection (FI) manifolds for the determination of cadmium and zinc (by FL), lead (RTP) and cobalt (CL). The analytical figures of merit are given for each manifold and results are presented for the determination of the four trace metals in seawater reference materials (NASS-5, SLEW-2) and Scheldt estuarine water samples.
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